In 1963, a Tanzanian schoolboy Erasto Bartholomeo Mpemba was doing a simple
school physics experiment and discovered that hot water freezes faster than
cold water.
This seems impossible because logically you’d say that as
the hot water cools, it would take some amount of time to reach the same
temperature as the cold water - and from that moment, take the same time as the
cold water did. Therefore, you’d argue, there is no way for the hot water to
freeze faster.
But Mpemba very definitely found that hot water freezes
faster than cold water IN SOME CIRCUMSTANCES.
His odd finding was initially ignored - but a few years
later, Mpemba asked a visiting physicist (Dr Denis Osborne) in question time
after a lecture - and while everyone (students and teachers) in the classroom
laughed at him, Osborne actually took him seriously - tried to repeat the
experiment and found that Mpemba was correct!
Osborne and Mpemba collaborated to write a paper - which was
published in Physics Education, Volume 4, Issue 3, pp. 172-175 (1969). The
paper goes a little deeper into the problem and eliminates the two most common
explanations (dissolved air and evaporation).
It turns out that there are a huge range of subtle effects
going on here - and it’s not ALWAYS the case that the hot water freezes first -
it’s sensitive to initial conditions…but if you follow the steps in the paper,
it is quite repeatable.
However, the reason for this weird
behavior had sparked off complicated discussions and there are at least ten
alternative explanations - and to this day, no single one of those possible
explanations are the single, widely accepted, cause.
There is a related paradoxical claim - the “inverse
Mpemba” in which heating warm water to a specific temperature can
take more time than heating cold water to that exact same temperature.
The best answer to both phenomena seems to be “Water Is Complicated!”
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